Pilia Carlo
UniCa About Professors and Researchers Carlo Pilia Research Research outcomes (IRIS)

Carlo Pilia

Synthesis of gamma-cyclodextrin substituted bis(acyl)phosphane oxide derivative (BAPO-gamma-CyD) serving as multiple photoinitiator and crosslinking agent

Chiappone A.;
2020-01-01

Abstract

A new multi-photoactive ?-cyclodextrin substituted bis(acyl)phosphane oxide derivative (BAPO-?-CyD) was successfully preparedviaa convergent synthesis using a phospha-Michael-addition, as confirmed by1H-,13C-,31P-NMR and IR spectroscopy and mass spectrometry. Kinetic studies carried out by photo-DSC and photo-rheology demonstrated its outstanding efficiency as a photoinitiator for free-radical polymerization. Remarkably, it is found that BAPO-?-CyD also acts as a crosslinking agent to convert monofunctional methacrylate monomers into self-standing thermosetting networks with extensive swelling capability in water.
2020
Inglese
CHEMICAL COMMUNICATIONS
56
35
4828
4831
4
WOS:000546458600016
2-s2.0-85084177225
32236208
Esperti anonimi
scientifica
Cyclodextrine; Photopolymerization; Hydrogels
sì
Cosola, A.; Conti, R.; Rana, V. K.; Sangermano, M.; Chiappone, A.; Levalois-Grutzmacher, J.; Grutzmacher, H.
1.1 Articolo in rivista
info:eu-repo/semantics/article
1 Contributo su Rivista::1.1 Articolo in rivista
262
7
partially_open
Files in This Item:
File Size Format  
Chem_Commun_2020_56_4828.pdf

open access

Type: versione editoriale
Size 2.24 MB
Format Adobe PDF
View/Open
2.24 MB Adobe PDF View/Open
d0cc01732a1.pdf

Solo gestori archivio

Type: versione editoriale
Size 813.38 kB
Format Adobe PDF
& nbsp; View / Open   Request a copy
813.38 kB Adobe PDF & nbsp; View / Open   Request a copy

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Questionnaire and social

Share on:
Impostazioni cookie